Materglass put some resin in water you will see that resin and water can stay seperate unless they are mixed and they emulsify. The milky or cloudy effect is usualy is usualy cause by allowing moisture or air to contaminate the pvb. This can be done by pressuring the water that may be left in the break into the pvb.
Some breaks will start to go milky after a short while and others never at all depends on if the contaminate can actually get to the pvb.
I do agree however that normaly the quicker you get to a repair the better it looks when finished.
Glass when broken does actualy start to oxidise on the broken surfaces but you will need a very big magnifying glass to see it.
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